Mixed-Metal Nickel–Iron Oxide Aerogels for Oxygen Evolution Reaction

نویسندگان

چکیده

Alkaline electrolyte membrane electrolyzers are a promising technology to efficiently produce clean hydrogen without the use of critical raw materials. At heart these electrocatalysts, which facilitate cathodic and anodic reactions, with latter oxygen evolution reaction (OER) being most sluggish. In recent years, aerogels have become very well-studied class materials due their unique properties, including high surface area. Until now, not been used catalyze OER by themselves but were mainly considered catalyst supports. Here, mixed-metal nickel–iron oxide synthesized modified epoxide route synthesis tested as catalysts. Depending on Ni/Fe ratio, they show catalytic activity low overpotential reach 10 mA cm–2 (at ? = 380 mV). This is beyond that existing state-of-the-art platinum group metal-free

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Nickel Oxide/Carbon Nanotubes as Active Hybrid Material for Oxygen Evolution Reaction

Carbon nanotubes are of great interest due to their high surface area and rich edge sites, which are favorable for wide applications. Here, a simple and efficient routine is presented by decoration of multi-wall carbon nanotube (MWCNT) with nickel oxide (NiO) nanoparticles.The morphologies of NiO-MWCNT  were  investigated  by  using scanning  electron  microscope  (SEM)  and energydispersive X-...

متن کامل

Metal Oxide/Pt Based Nanocomposites as Electrocatalysts for Oxygen Reduction Reaction

Fuel cell is a promising choice for clean energy because of its eco-friendly system, high energy conversion efficiency and high power density. Recently, much of the research work is focused on the system of combining metal oxides to increase the durability and surface area and to reduce the cost. In this study, among the various fabrication methods, we used the precipitation method to synthesis...

متن کامل

Electrodeposition of platinum nanoparticles on reduced graphene oxide as an efficient catalyst for oxygen reduction reaction

Reduced graphene oxide film was synthesized on a glassy carbon electrode by electro reduction of graphene oxide powders in aqueous solution. Then platinum nano particles were deposited on reduced graphene oxide film that was deposited on the glassy carbon electrode via electro reduction of platinum salt. The Physical morphology of the platinum on reduced graphene oxide film was evaluated by sca...

متن کامل

Redox switching and oxygen evolution at oxidized metal and metal oxide electrodes: iron in base.

Outstanding issues regarding the film formation, redox switching characteristics and the oxygen evolution reaction (OER) electrocatalytic behaviour of multicycled iron oxyhydroxide films in aqueous alkaline solution have been revisited. The oxide is grown using a repetitive potential multicycling technique, and the mechanism of the latter hydrous oxide formation process has been discussed. A du...

متن کامل

The Oxygen Evolution Reaction on Passive Oxide Covered Transition Metal Electrodes in Alkaline Solution. Part III – Iron

The kinetics of the oxygen evolution reaction (OER) at passive oxide covered polycrystalline Fe electrodes in aqueous alkaline solution were examined using both dc steady state polarisation and ac impedance techniques. It proved difficult to obtain reproducible polarisation data for bright anodes, and so an electrochemical pre-treatment routine was devised. Upon ageing of a given electrode spec...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: ACS Catalysis

سال: 2022

ISSN: ['2155-5435']

DOI: https://doi.org/10.1021/acscatal.2c03351